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Organic chemistry: methane to macromolecules

Author: Roberts, John D. and Stewart, Ross and Caserio,
Url: http://caltechbook.library.caltech.edu/116/
Format: Pdf
Year: 1971
Category: Organic Chemistry
Clicks: 2397

The success achieved by this book\'s forerunners, Basic Principles of Organic Chemistry and Modern Organic Chemistry, was to a considerable extent due to the rigor with which the subject of organic chemistry was presented. In the present work we have tried to paint an interesting, relevant, and up-to-date picture of organic chemistry while retaining the rigorous approach of the earlier books. Organic chemistry sometimes appears to be enormously complex to the beginning student, particularly if he must immediately grapple with the subjects of structural isomerism and nomenclature. We have attempted to avoid this difficulty in the following way. Chapter 1 briefly relates carbon to its neighbors in the Periodic Table and reviews some fundamental concepts. Chapter 2 deals with the four C1 and C2 hydrocarbons-methane, ethane, ethene, and ethyne-and discusses their conformational and configurational properties and some of their chemical reactions. The reader thus makes an acquaintance with the properties of some important organic compounds before dealing in an open-ended way with families of compounds-alkanes, alcohols, etc. A heavy emphasis on spectroscopy is retained but the subject is introduced somewhat later than in the earlier books. Important additions are chapters dealing with enzymic processes and metabolism and with cyclization reactions. Many of the exercises of the earlier books have been retained and have been supplemented with drill-type problems. It seems a shame to burden the mind of the beginning student with trivial names, some of them quite illogical, and throughout we have stressed IUPAC nomenclature, which is both logical and easy to learn. The instructor, who may well carry lightly the excess baggage of redundant names, may occasionally find this irritating but we ask him to consider the larger good. As a further aid to the student, each chapter concludes with a summary of important points.

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